You can specify which protocols are used using SSLConfiguration property:
using (Imap client = new Imap())
{
// Allow TLS only:
client.SSLConfiguration.EnabledSslProtocols = SslProtocols.Tls;
client.ConnectSSL("imap.gmail.com");
SslProtocols protocols = ((SslStream) client.ReadStream).SslProtocol;
if (protocols != SslProtocols.Tls)
throw new Exception("This is just to show that TLS is used. " +
"No need for such check in the real application.");
client.UseBestLogin("pat@gmail.com", "password");
client.Close();
}