This error comes from your SMTP server (not Mail.dll itself).
I think this error coming from outlook.com means that the user whose credentials you specified in the SMTP connection cannot submit messages on behalf of the user specified in the From/Sender MIME headers -or- the FROM SMTP command.
You should be using the same from (MailBuilder.From
) for your message as you use in logging in (Smtp.UseBestLogin
).